化學系所 

電化學 

223 U0130 3學分 

任課教師:蘇玉龍教授
 

本課程為化學系三、四年級及研究所碩、博士班之選修課程。

 

一、 宗旨:介紹電化學的基本原理,學術研究使用的技術及在工業界的
          應用。

 

二、 大綱:

 

(A)Introduction

(a)  electrochemical cell

(b)  the Nernst equation

(c)  surface and bulk

(d)  double layer

(e)  surface phenomena

(f)  heterogeneous electron transfer

(g)  mass transfer

 

(B) Chronoamperometry

 

(C) Chronocoulometry

 

(D) Voltammetry

(a)  single sweep voltammetry

(b)  polarography

i.  dropping mercury electrode

ii.  pulse polarography

(c)  cyclic voltammetry

i.  reversible and irreversible reactions

ii.  bulk and adsorbed species

iii.  thin layer

iv.  CV diagnostics

 

(E)  Hydrodynamic Methods

 

(F)  Spectroelectrochemistry

 

(G)  Electrocatalysis

 

(H) Chemically Modified Electrodes

(a)  adsorption

(b)  covalent bond

(c)  electropolymerization

(d)  polyelectrolyte

(I) Applications

 

三、 參考資料(圖書館保留):

 

1.  A. J. Bard and L. Faulkner, Electrochemical Methods. Fundamentals and Application, Wiley, NY, 1980

2.  P. H. Rieger, Electrochemistry, 2nd ed. Chapman & Hall, NY, 1994.

3.  R. N. Adams, Electrochemistry at Solid Electrodes, Marcel Dekker, NY, 1969.

4.  D. T. Sawyer, A. Sobkowiak, J. L. Roberts, Electrochemistry for Chemist, 2nd ed. Wiley, NY, 1995.

5.  P. T. Kissinger and W. R. Heineman, Laboratory Techniques in Electroanalytical Chemistry, Marcel Dekker, NY, 1984.

6.  A. J. Bard, Integrated Chemical System, Wiley, NY. 1994.

7.  J. OM Bockris and A. K. N. Reddy, Modern Electrochemistry, vol. 1-29, Plenum, NY. 1970-1996.

8.  Electrochemical Surface Science, M. P. Soriaga ed., ACS Symposium Series 378, American Chemical Society, Washington D. C., 1988.

9.  Electrochemistry, Past and Present, J. T. Stock and M. V. Orna ed., ACS symposium Series 390, American Chemical Society, Washington D. C., 1989

10.  Electroanalytical Chemistry, A. Series of Advances, A. J. Bard. ed. Marcel Dekker, NY.