台灣大學89學年第二學期  開課系所:化學系 (大學部選修)  

課程名稱:化學鍵 (2學分)

課程編號:203 12910
授課對象:化學系大一以上選修 授課老師:陳竹亭教授、金必耀教授

Chemical Structure and Bonding                   Spring, 2001          

New homepage!!

 

CONTENTS

Atomic Structure

l   Historical discoveries for Atomic Structure

l   Bohr Theory of Hydrogen Atom

l   Absorption & Emission Spectra of Hydrogen Atom

l   Dual Properties of Electromagnetic Radiation and Matter

l   The Wave Equations and Hydrogen Atom

l   Many-Electron Atoms and Atomic Energy States

l   Atomic Properties and Configuration

 

Molecular Properties

l   Lewis Structures

l   Ionic and Covalent Characters

l   Multiple Bonds

l   Resonance

l   Molecular Geometry

l   Molecular Symmetry

 

Valence Bond Theory

l   VBT for Small Molecules

l   Hybrid Orbitals

l   Boranes

 

Molecular Orbital Theory

l   Molecular orbital Energy Levels and Molecular Spectroscopy

l   Homonuclear Diatomic Molecules

l   Heteronuclear Diatomic Molecules

l   MOT for Small Molecules

l   Photoelectron Spectra of Molecules

l   Frontier Orbital Concept

l   Transition Metal Complexes

 

Electronic Structures of Polyatomic Molecules

l   Molecular Orbitals for Triatomic Molecules and Walsh Correlation Diagram

l   Molecular Orbitals for BH3 and NH3

l   Molecular Orbitals for CH4, CO2, and XeF4

l   Huckel Molecular Orbital Theory of Conjugated Systems

l   Semi-Empirical Molecular Orbital Theory

l   Symmetry Rules for Chemical Reactions

 

Transition-Metal Complexes

l   Effective Atomic Number and Stability

l   Metal-Metal Bonds

l   Ligand Field Theory for Octahedral Complexes

l   Ligand Field Theory for Square-Planar Complexes

l   Ligand Field Theory for Tetrahedral Complexes

l   The Shapes of Transition-Metal Complexes

 

Chemical Bonding in Polymers and Solids

l   Energy Band in Metals

l   Electronic Structures of Conjugated Polymer

l   Ionic Solids and Lattice Energy

l   Elemental and Molecular Solids

l   Nonmetallic Network Solids