Peng, Shie-Ming
B.S. National Taiwan University
1970
Ph.D. University of Chicago
1975
Fax (02) 23636359
smpeng@chem35.ch.ntu.edu.tw
S.-M. Peng's Group Homepage
Inorganic Chemistry
Born 1949.  B.S., 1970, National Taiwan Univ.; Ph.D., 1975, Univ. of Chicago.  Research Associate, 1975-76, Northwestern Univ.  Associate Professor, 1976-80; Professor, 1980-; Chairman, 1987-90, Dept. of Chemistry, NTU.  Humboldt Research Fellow of Germany, 1983-84.  Research Fellow, 1982-; Acting Director, 1985-87, Institute of Chemistry, Academia Sinica; Academician, 1998, Academia Sinica. 
 

Research Interests

1. Synthesis and characterizations of metal complexes which have delocalized ground states and possess unusual redox, spectroscopic, magnetic, and structural properties.  e.g. metal complex of o-quinonediimine, diiminosuccino-nitrile, and fully conjugated macrocycles. 
2. Synthesis and structural, photochemical studies of d10 metal clusters.  e.g. d10 metal clusters of sulfonylamido, polyphosphino, and acetylido bridged ligands. 
3. The study of oligonuclear metal-metal multiple bond and molecular metalwire: The number of metal atoms in a string is now up to nine.

Selected Publications

  • Wang, C.; Lo, W.; Chou, C.; Lee, G.; Chen, J.; Peng, S. ¡§Synthesis, Crystal Structures, and Magnetic Properties of a Series of Linear Pentanickel(II) Complexes¡¨ Inorg. Chem. 1998, 37, 4059-4065.
  • Yang, M.; Lin, T.; Chou, C.; Lee, H.; Chang, H.; Lee, G.; Leung, M.; Peng, S. ¡§New Oligo-a -pyridylamino Ligands and Their Metal Complexes¡¨ Chem. Commun. 1997, 2279-2280.
  • Shieh, S.; Chou, C.; Lee, G.; Wang, C.; Peng, S. ¡§Linear Pentanuclear Complexes Containing a Chain of Metal Atoms: [Co5II(m 5-tpda)4(NCS)2] and [Ni5II(m 5-tpda)4Cl2]¡¨ Angew. Chem., Int. Ed. Engl. 1997, 36, 56-59.
  • Sheu, J.; Lin, C.; Chao, I.; Wang, C.; Peng, S. ¡§Linear Trinuclear Three-Centered Metal-Metal Multiple Bonds: Synthesis and Crystal Structure of [M3(dpa)4Cl2][M=RuII, or RhII, dpa=bis(dipyridyl)-amido anion]¡¨ Chem. Commun. 1996, 315-316.
  • Tzeng, B.; Lo, W.; Che, C.; Peng, S. ¡§Photophysical Properties, Crystal Structure, and Host-Guest Interaction of a Luminescent Tetranuclear Gold(I)-Phenylacetylide Complex with a Supramolecular Phosphine Ligand¡¨ Chem. Commun. 1996, 181-182.
  • Chern, S.; Lee, G.; Peng, S. ¡§Unique Eclipsed Cofacial Oligomeric Complexes of Rhodium Containing Three-layered Bonding of 9,-10-Phenanthroquinonediimine¡¨ J. Chem. Soc., Chem. Commun. 1994, 1645-1646.
  • Yang, E.-C.; Cheng, M.-C.; Tsai, M.-S.; Peng, S.-M. ¡§Structure of a Linear Unsymmetrical Trinuclear Cobalt(II) Complex with a Localized CoII-CoII Bond: Dichlorotetrakis[m 3-bis(2-pyridyl)amido]trico-balt(II)¡¨ J. Chem. Soc., Chem. Commun. 1994, 2377-2378.
Inorganic Chemistry

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Last modified: Tue Feb 24 14:19:38 1998