無機化學

Peng, Shie-Ming

Inorganic Chemistry 
　

研究興趣

1. 具有電子非定域化及氧化還原、光譜、磁性、構造上具特異性之無機錯合物，例如鄰-?二亞胺、二亞胺丁二?及全共軛之大環錯合物。 
2. d10金屬簇錯合物之合成，構造及光化學研究，例如以磺醯胺、多膦基及炔陰基等為橋基之d10金屬簇。 
3. 多核金屬-金屬多重鍵及分子金屬線之研究，例如已合成三到九個金屬串之錯合物。 

Research Interests

1. Synthesis and characterizations of metal complexes which have delocalized ground states and possess unusual redox, spectroscopic, magnetic, and structural properties.  e.g. metal complex of o-quinonediimine, diiminosuccino-nitrile, and fully conjugated macrocycles. 
2. Synthesis and structural, photochemical studies of d10 metal clusters.  e.g. d10 metal clusters of sulfonylamido, polyphosphino, and acetylido bridged ligands. 
3. The study of oligonuclear metal-metal multiple bond and molecular metalwire: The number of metal atoms in a string is now up to nine.

• Wang, C.; Lo, W.; Chou, C.; Lee, G.; Chen, J.; Peng, S. “Synthesis, Crystal Structures, and Magnetic Properties of a Series of Linear Pentanickel(II) Complexes” Inorg. Chem. 1998, 37, 4059-4065.
• Yang, M.; Lin, T.; Chou, C.; Lee, H.; Chang, H.; Lee, G.; Leung, M.; Peng, S. “New Oligo-a -pyridylamino Ligands and Their Metal Complexes” Chem. Commun. 1997, 2279-2280.
• Shieh, S.; Chou, C.; Lee, G.; Wang, C.; Peng, S. “Linear Pentanuclear Complexes Containing a Chain of Metal Atoms: [Co₅^II(m ₅-tpda)₄(NCS)₂] and [Ni₅^II(m ₅-tpda)₄Cl₂]” Angew. Chem., Int. Ed. Engl. 1997, 36, 56-59.
• Sheu, J.; Lin, C.; Chao, I.; Wang, C.; Peng, S. “Linear Trinuclear Three-Centered Metal-Metal Multiple Bonds: Synthesis and Crystal Structure of [M₃(dpa)₄Cl₂][M=Ru^II, or Rh^II, dpa=bis(dipyridyl)-amido anion]” Chem. Commun. 1996, 315-316.

• Tzeng, B.; Lo, W.; Che, C.; Peng, S. “Photophysical Properties, Crystal Structure, and Host-Guest Interaction of a Luminescent Tetranuclear Gold(I)-Phenylacetylide Complex with a Supramolecular Phosphine Ligand” Chem. Commun. 1996, 181-182.
• Chern, S.; Lee, G.; Peng, S. “Unique Eclipsed Cofacial Oligomeric Complexes of Rhodium Containing Three-layered Bonding of 9,-10-Phenanthroquinonediimine” J. Chem. Soc., Chem. Commun. 1994, 1645-1646.
• Yang, E.-C.; Cheng, M.-C.; Tsai, M.-S.; Peng, S.-M. “Structure of a Linear Unsymmetrical Trinuclear Cobalt(II) Complex with a Localized Co^II-Co^II Bond: Dichlorotetrakis[m ₃-bis(2-pyridyl)amido]trico-balt(II)” J. Chem. Soc., Chem. Commun. 1994, 2377-2378.