須知: 授課對象以主修農業化學系及植物系的學生為主,其他欲選修此課者須經過授課教師同意。 1 一年課程,上下學期各三學分,每週上課四小時,上課時間為週三及週五10:10-12-00。習題講演及討論隔週上課兩小時,時間另定。 2 實驗每學期一學分,上課時間為週一(植物)週四(農化)14:10-15-00。
參考資料(化學系圖書館):
教科書: Chemistry-Molecules, Matter, and Change, 4th Edition, 2000, Lorretta Jones & Peter Atkins, Freeman and Co. (歐亞書局)
課程大綱
上學期
(一) 物質的世界 Matter/Chemical Change/Stoichiometry, Chapters 1-4
1 introduction, history of modern chemistry, elements, compounds, molecules, and ions, the periodic table and nomenclature
2 chemical reactions, chemical equations, reaction classifications
3 atomic and molar masses, the mole, mass spectroscopy, chemical formula, stoichiometry
(二) 粒子世界的規律 Gases and Molecular Dynamics, Chapters 5
1 the ABC (Avogadro, Boyle, Charles) Laws, the ideal gas law, the Dalton's law of partial pressures
2 the kinetic model
3 effusion and diffusion, intermolecular collision, real gases
(三) 能量的世界 Thermodynamics, Chapter 6
1 energy, enthalpy, thermodynamics of gases, thermochemistry
2 the 1st law of thermodynamics, calorimetry, Hess's law
(四) 物質的組成 Atomic Structure/PeriodicTable, Chapter 7
1 atomic spectrum of hydrogen atom, the Bohr model, dual properties of matter,
2 quantum mechanical description, particle in a box, the wave equation of hydrogen
3 atomic orbitals, pauli principle, Hunds rule, electronic configurations, periodic trends and atomic properties
(五) 原子為什麼會結合 Chemical Bonding, Chapter 8
1 ions and ionic compounds
2 covalent bonds, partial ionic character, bond energies,Lewis structures, resonance, hybridization
3 odd-electron species, Lewis concept for chemical reactions
(六) 分子的形狀 Molecular Structure, Chapter 9
1 elctronegativity, bond polarity, dipole moments, VSEPR model
2 Valence Bond Theory and Molecular Orbital Theory
(七) 從微觀世界到宏觀世界 Liquids and Solids, Chapter 10
1 intermolecular forces, water, liquid state and liquid crystals
2 closest packing, structure and bonding of metals, ionic solids, carbon & silicon, molecular solids, lattice defects, phase diagram
(八) 生命之源 carbon - resource of life, Chapter 11
1 hydrocarbon, basic organic compounds
2 natural and artificial polymers
下學期
(九) 溶液的性質 solutions, Chapter 12
1 solvents and solutes, solubility
2 Factors affecting solubility
3 colligative properties
(十) 化學反應如何進行 Chemical Kinetics, Chapter 13
1 reaction rates & rates law, 1st order & psudo first order rate laws,
2 reaction mechanisms, steady state approximation, activation energy, reaction intermediates
3 collision theory, catalysis
(十一) 大自然的制約機制 Chemical Equilibrium, Chapter 14
1 equilibrim condision, measurement for equilibrium, equlibrium expressions
2 the concept of activity, Le Chatelier's Principle
3 equilibrium systems and equilibrium problems
(十二) 水溶液的化學 Acids and Bases/Aqueous Equilibria Chapter 15, 16
1 the nature of acides & bases, acid strength, strong and weak acid solutions, polyprotic acids, acid-base salts
2 common ion effect, buffered solutions, titration, indicators
3 solubility equilibria, precipitation and quantitative analysis, complex ion equilibria
(十三) 化學反應為何發生 Thermodynamics(II), Chapter 17
1 spontaneous reactions, entropy,
2 free energy
(十四) 電子之舞 Electrochemistry, Chapter 18
1 Galvanic cells, reduction potential, cell potential and equilibria
2 batteries, electrolysis, corrosion,
(十五) 從一理中窺萬象 The Chemistry of Metals and Nonmetals, Chapter 19, 20, 21
1 representative elements 1A-7A
2 metalloid chemistry
3 Transition Metal chemistry
(十六)次原子世界 Nuclear Chemistry, Chapter 22
1 nuclear stability and radioactive decay, nuclear transformation
2 kinetics, thermodynamics
3 nuclear fission and nuclear fussion