國立臺灣大學化學系

利用過渡金屬錯合物或有機金屬為材料，尋找這些分子於催化反應中新的應用，以發展出新的催化化學，並將有利於綠色化學的發展。

研究員 (104年迄今)；副研究員 (100-104年)；助研究員 (95-100年)；美國明尼蘇達州維諾那州立大學學士(83年)；肯德基大學博士(89年)；加州大學聖塔芭芭拉分校博士後研究員(89-90年)；加拿大渥太華大學講師兼博士後研究員(93-94年)；

2010中國化學會青年化學家獎；2013日本化學年會亞洲國際研討會傑出講學獎；第十五屆財團法人水木化學文教基金會傑出青年學者獎；

1. Hsu, Y.-C.; Shen, J.-S.; Lin, B.-C.; Chen, W.-C.; Chan, Y.-T.; Ching, W.-M.; Yap, G. P. A.; Hsu, C.-P.; Ong, T.-G. Isolation of Tridentate Acyclic Bis(Pyridine)carbodicarbene and Further Studies on Its Structural Implications and Reactivities. Angew. Chem. Int. Ed. 2014, Accepted for publication.


2. Yu, M.-S.; Lee, W.-C.; Chen, C.-H.; Tsai, F.-Y.; Ong, T.-G. Controlled Regiodivergent C-H Bond Activation of Imidazo[1,5-a]pyridine via Synergistic Cooperation between Aluminum and Nickel. Organic Letters, 2014, Accepted for publication. .


3. Chen, W.-C.; Lai, Y.-C.; Shih, W.-C.; Yu, M.-S.; Yap, G. P. A.; Ong, T.-G. Mechanistic Study of the Regioselective Switch for Hydroheteroarylation of Styrene Catalyzed by Bimetallic Ni-Al via C-H Activation. Chem.-Eur. J. 2014, 20, 8099.


4. Huang, H.-J.; Lee, W.-C.; Yap, G. P. A.; Ong, T.-G. Synthesis and Characterization of Amino-NHC Coinage Metal Complexes and Application for C-H Activation of Caffeine. J. Organomet. Chem. 2014, 761, 64.


5. Tai, C.-C; Yu, M.-S.; Chen, Y.-L.; Chuang, W.-H.; Lin T.-H.; Yap, G. P. A.; Ong, T.-G. Synthesis of a Guanidine NHC complex and its Application in Borylation Reactions. Chem. Commun. 2014, 50, 4344.


6. Lee, W.-C.; Wang, T.-H.; Ong, T.-G. Ligand promoted Pd-catalyzed dehydrogenative alkenylation of hetereoarenes. Chem. Commun. 2014, 50, 3671.


7. Chen, C.-C.; Lee, C.-Y.; Lin, B.-C.; Hsu, Y.-C.; Shen, J.-S.; Hsu, C.-P.; Yap, G. P. A.; Ong, T.-G. The Elusive Three-Coordinate Dicationic Hydrido Boron Complex. J. Am. Chem. Soc. 2014, 136, 914.


8. Lee, W.-C.; Wang, C.-H.; Lin Y.-H.; Shih, W.-C.; Ong, T.-G. Tandem Isomerization and C–H Activation: Regioselective Hydroheteroarylation of Allylarenes. Organic Letters, 2013, 15, 5358.


9. Chen, C. T.; Chen, C. H.; Ong, T.-G. Complementary Helicity Interchange of Optically Switchable Supramolecular-Enantiomeric Helicenes with (−)-Gel-Sol-(+)-Gel Transition Ternary Logic. J. Am. Chem. Soc 2013, 135, 5294.


10. Chen, W. C.; Hsu, Y. C.; Lee, C. Y.; Yap, G. P. A.; Ong, T.-G. Synthetic Modification of Acyclic Bent Allenes (Carbodicarbenes) and Further Studies on Their Structural Implications and Reactivities. Organometallics, 2013, 32,2435.


11. Titel, J.; Chen, W. C.; Michel, S.; Korobkov, I.; Ong, T.-G. Richeson, D. S. Solid-State Thermolysis of a fac-Rhenium(I) Carbonyl Complex with a Redox Non-Innocent Pincer Ligand. Chem.-Eur. J. 2013, 19, 4278.


12. Chen, W. C.; Hsu, Y. C.; Shih, W. C.; Lee, C. Y.; Chuang, W. H.; Tsai, Y. F.; Chen, P. P. Y.; Ong, T.-G. Metal-free arylation of benzene and pyridine promoted by amino-linked nitrogen heterocyclic carbenes. Chem. Commun. 2012, 48, 6702.


13. Liu, Y. M.; Lin, Y. C.; Chen, W. C.; Cheng, J. H.; Yap, G. P. A. Sun S. S; Ong, T.-G. Synthesis and Characterization of a para-Pyridine Linked NHC Palladium Complexes and their Studies for Heck-Mizoroki Coupling Reaction. Dalton Transactions, 2012, 41, 7382.


14. Shih, W. C.; Chen, W. C.; Lai, Y. C.; Yu, M. Y.; Ho, J. J.; Yap, G. P. A.; Ong, T.-G. The Regioselective Switch for Amino-NHC Mediated C-H Activation of Benzimidazole via Ni-Al Synergistically Catalysis. Organic Letters, 2012, 14, 2046.


15. Tai, C. –C.; Chang, Y. –T.; Tsai, J. –H.; Jurca, T.; Yap, G. P. A.; Ong, T. –G. Subtle Reactivities of Boron and Aluminum Complexes with Amino-Linked N-Heterocyclic Carbene Ligation. Organometallics, 2012, 31, 637.


16. Wang, C.-H; Shih, W.-C.; Chang, H.-C.; Kuo, E.; Hung, W.-C.; Ong, T.-G.; Li, W.-S. Preparation and Characterization of Amino-Linked Heterocyclic Carbene Palladium, Gold, and Silver Complexes: Applications in Anticancer Agents via Triggering Apoptotic Cell Death. J. Med. Chem. 2011, 54, 5245.


17. Li, C.-Y.; Kuo, Y.-Y; Tsai, J.-H.; Yap, G. P. A.; Ong, T.-G. Amine-Linked N-Heterocyclic Carbene: The importance of an Pendant Free Amine Auxiliary in Assisting the Catalytic Reaction. Chem. Asian J. 2011, 6, 1520.


18. Tsai, J.-H.; Lin, S.-T.; Yang, R. B.G.; Yap, G. P. A.; Ong, T.-G. The Two-way Street Transformation of Boronium and Borane Complexes Facilitated by Amino-Linked N-Heterocyclic Carbene. Organometallics 2010, 29, 4004.


19. Tsai, C. –C.; Shih, W.-C.; Fang, C.-H.; Li, C.-Y.; Ong, T.-G.; Yap, G. P. A. Bimetallic Nickel Aluminun Mediated Para-Selective Alkenylation of Pyridine: Direct Observation of η2,η1-Pyridine Ni(0)−Al(III) Intermediates Prior to C−H Bond Activation. J. Am. Chem. Soc. 2010, 132, 11887.


20. Hu, Y.-C.; Liang, C.-F.; Tsai, J.-H.; Yap, G. P. A.; Chang, Y.-T.; Ong, T.-G. Zirconium Complexes Supported by Imidazolones: Synthesis, Characterization, and Application of Precatalysts for the Hydroamination of Aminoalkenes. Organometallics 2010, 29, 3357.


21. Hu, Y.-C.; Tsai, C.-C.; Shih, W.-C.; Yap, G. P. A.; Ong, T.-G. The Zirconium Benzyl Mediated C-N Bond Cleavage of an Amino-Linked N-Heterocyclic Carbene. Organometallics 2010, 29, 516.


22. Shih, W. -C.; Wang, C.-H.; Chang, T.-T.; Yap, G. P. A.; Ong, T-G. Synthesis and Structure of an Amino- Linked N-Heterocyclic Carbene and the Reactivity of its Aluminum Adduct. Organometallics 2009, 47, 1060.


23. Huang, Y.-P.; Tsai, C.-C.; Shih, W.-C.; Chang, Y.-C.; Lin, S.-T.; Yap, G. P. A.; Chao, I.; Ong, T-G. Kinetic and Thermodynamic Study of Syn—Anti Isomerization of Nickel Complexes Bearing Amino-Linked N-Heterocyclic Carbene Ligands: The Effect of the Pendant Arm of the NHC. Organometallics 2009, 28, 4316.


24. Rowley, C. N.; Ong, T-G.; Priem, J.; Richeson, D. S.; Woo, T. K. Analysis of the Critical Step in Catalytic Carbodiimide Transformation: Proton Transfer from Amines, Phosphines, and Alkynes to Guanidinates, Phosphaguanidinates, and Propiolamidinates with Li and Al Catalysts. Inorg. Chem. 2008, 47, 12024.


25. Rowley, C. N.; Ong, T-G.; Priem, J.; Woo, T. K.; Richeson, D. S. Amidolithium and Amidoaluminum Catalyzed Synthesis of Substituted Guanidines: An Interplay of DFT Modeling and Experiment. Inorg. Chem. 2008, 47, 9660.


26. Lavoie, N.; Ong, T. G.; Gorelsky, S. I.; Korobkov, I.; Yap, G. P. A.; Richeson, D. S. Bis(imido) W(VI) complexes chelated by N,N '-Disubstituted 1,8-diamidonaphthalene: An analysis of bonding, isocyanate insertion, and Al-Me transfer. Organometallics 2007, 26, 6586.


27. Ong, T. G.; O'Brien, J. S.; Korobkov, I.; Richeson, D. S. Facile and atom-efficient amidolithium-catalyzed C-C and C-N formation for the construction of substituted guanidines and propiolamidines. Organometallics 2006, 25, 4728.


28. Said, F. F.; Ong, T. G.; Bazinet, P.; Yap, G. P. A.; Richeson, D. S. Linking hydrogen dicarboxylate synthons with substituted guanidinium cations: Transforming rings and chains into two- and three-dimensional structures. Cryst. Growth Des. 2006, 6, 1848.


29. Said, F. F.; Bazinet, P.; Ong, T.-G.; Yap, G. P. A.; Richeson, D. S. Hydrogen Bonding Motifs of N,N',N' '-Trisubstituted Guanidinium Cations with Spherical and Rodlike Monoanions: Syntheses and Structures of I^-, I₃^-, and SCN- Salts. Cryst. Growth Des. 2006, 6, 258.


30. Said, F. F.; Ong, T.-G.; Yap, G. P. A.; Richeson, D. Strong and Weak Hydrogen-Bonding Interactions in the Structures of N,N',N' '-Trisubstituted Guanidinium Chlorides and Bromides. Cryst. Growth Des. 2005, 5, 1881.


31. Ong, T. G.; Yap, G.; Richeson, D. S. Catalytic C-N bond metathesis of carbodiimides by group 4 and 5 imido complexes supported by guanidinate ligands. Chem. Commun. 2003, 2612.


32. Ong, T. G.; Yap, G.; Richeson, D. S. Catalytic Construction and Deconstruction of Guanidine: Ti-Mediated Guanylation of Amines and Transamination of Guanidines. J. Am. Chem. Soc. 2003, 125, 8100.


33. Ong, T. G.; Yap, G.; Richeson, D. S. Redefining the Coordination Geometry and Reactivity Guanidinate Complexes by Covalently Linking the Guanidine ligands. Organometallics 2003, 22, 387.


34. Ong, T. G.; Yap, G.; Richeson, D. S. Formation of a Guanidinate-Supported Titanium Imido Complex: A Catalyst for Alkyne Hydroamination. Organometallics 2002, 21, 2839.


35. Ong, T. G.; Wood, D.; Yap, G.; Richeson, D. S. Transformations of Aryl Isocyanide on Guanidinate-Supported Organozirconium Complexes To Yield Terminal Imido, Iminoacyl, and Enediamido Ligands. Organometallics 2002, 21, 1.


36. Ong, T.-G.; Yap, G. P. A.; Richeson, D. S. Formation of a Guanidinate-Supported Titanium Imido Complex: A Catalyst for Alkyne Hydroamination. Organometallics 2002, 21, 2839.