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國立臺灣大學化學系

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彭之皓


彭之皓
教授
化學館 A622室
電話: 02-3366-9545
傳真:
研究興趣

本實驗室的研究涵括了無機化學、有機金屬化學、與高分子化學。我們一方面從有機金屬錯合物的設計與合成著手,研究活性自由基聚合反應的機理與應用。最近更開發出以有機物為控制劑的新系統,使得反應更環保,更經濟,也更具實用性。基於此系統,我們進一步合成出各式的嵌段共聚物,並測試其物性與化性,評估這些新材料作為各種助劑如:界面活性劑、乳化劑、增韌劑、接著劑的可能性。未來期望這部分的研究可以產業化,對國內的產業做出實質的貢獻。


另一方面,我們也與其他團隊合作,以多酚酮結構作為基礎,開發新型態的直線型多氧配基。並以這些多氧配基與鑭系金屬進行反應,形成雙核的鑭系錯合物,探討鑭系金屬之間的作用力,並希望藉由一系列雙核鑭系錯合物的比較,研究鑭-鑭之間及鑭系與過渡金屬之間的鍵結,甚至進而探討f軌域的作用力。此外藉由多酚酮結構的延伸,我們也期望合成出四核的鑭系錯合物,這將會是第一個鑭系金屬所形成的直線型金屬串錯合物,對於有機金屬,配位化學,及結構化學都會有很大的貢獻。

簡歷

  • 1999年 國立臺灣大學化學系學士

  • 2001年 國立臺灣大學化學系碩士

  • 2003-2004年 國立臺灣大學化學系助教

  • 2009年 美國賓州大學化學系博士

  • 2009-2011年 美國卡內基美濃大學博士後研究員

  • 2011-2016年 國立清華大學化學系助理教授

  • 2015-2018年 國立清華大學產學營運總中心智財技轉組組長

  • 2016-2021年 國立清華大學化學系副教授

  • 2021-2022年 國立清華大學化學系教授

  • 2022-迄今 國立臺灣大學化學系教授

榮譽事項

  • 2016 年POLMER期刊 "第十届冯新德高分子奖最佳文章提名奖"

  • 2017 年日本高分子學會 "國際優秀年輕學者邀請講座"

  • 2018 年財團法人水木化學文教基金會 "傑出青年學者獎"

  • 2019 年科技部 "優秀年輕學者研究計畫"

  • 2019 年中華民國高分子協會 "傑出青年高分子科技獎"

  • 2019 年中國化學會 "傑出青年化學家獎章"

研究內容
代表著作

  1. Wang, F.-S.; Lin, S.-H.; Zheng, G.-H.; Li, M.-H.; Cheng, Y.-C.; Peng, C.-H.* "Coordination of Azobisisobutyronitrile with Cobalt Complexes in Cobalt-Mediated Radical Polymerization Disclosed by Linear Correlation between the Equilibrium Constant and Half-Wave Potential" Macromolecules 2022, 55, 4276.

  2. Chang, C.-W.; Jen, Y.-Y.; Tang, S.-C.; Zhang, P.; Chen, C.; Peng, C.-H.* "Reversible-deactivation radical polymerization of vinyl acetate mediated by tralen, an organomediator" Polym. Chem. 2021, 12, 5159.

  3. Benchaphanthawee, W.; Peng, C.-H.* "Organo-Cobalt Complexes in Reversible-Deactivation Radical Polymerization" Chem. Rec. 2021, 21, 3628.

  4. Wang, F.-S.; Tsai, Y.-W.; Xie, M.-Q.; Peng, C.-H.* "Computation-Assisted Investigation of Polymer Kinetics: Mechanism of the Hybridization of Cobalt-Mediated Radical Polymerization and Atom Transfer Radical Polymerization" Macromolecules 2020, 53, 10855.

  5. Chen, S.-J.; Tang, S.-C.; Zhang, P.; Chen, C.*; Peng, C.-H.* "Aluminum Tralen Complex Mediated Reversible-Deactivation Radical Polymerization of Vinyl Acetate" ACS Macro Lett. 2020, 9, 1423.

  6. Wu, Z.; Peng, C.-H.*; Fu, X.* "Tacticity control approached by visible-light induced organocobalt-mediated radical polymerization: the synthesis of crystalline poly(N, N-dimethylacrylamide) with high isotacticity" Polym. Chem. 2020, 11, 4387.

  7. Wu, Z.; Wang, Z.; Wang, B.-W.; Peng, C.-H.*; Fu, X.* "Visible-Light-Induced Living/ Controlled Radical Copolymerization of 1‑Octene and Acrylic Monomers Mediated by Organocobalt Complexes" Macromolecules 2020, 53, 212.

  8. Chang, H.-C.; Li, J.-Q.; Lin, C.-K.; Hsu, Y.-J.; Tu, T.-H.; Hsieh, Y.-L.; Hsu, H.-H.; Lee, G.-H.; Liu, Y.-H.; Peng, C.-H.* "Development of dipyridine based coordinative polymers for reusable heterogeneous catalysts" J. Chin. Chem. Soc. 2019, 66, 1119.

  9. Su, C.-H.; Wu, Z.; Lin, C.-K.; Han, H.-A.; Chen, Y.-A.; Chou, P.-T.; Fu, X.*; Peng, C.-H.* "Polystyrene with Persistently Enhanced Fluorescence: Photo-Induced Atom Transfer Radical Polymerization Using a Pyrene-Based Initiator" ChemPhotoChem 2019, 3, 1153.

  10. Lu, H.-H.; Huang, C.-H.; Shiue, T.-Y.; Wang, F.-S.; Chang, K.-K.; Chen, Y.; Peng, C.-H.* "Highly Efficient Gene Release in Spatiotemporal Precision Approached by Light and pH Dual Responsive Copolymers" Chem. Sci. 2019, 10, 284.

  11. Wang, F.-S.; Wang, T.-F.; Lu, H.-H.; Ao-Ieong, W.-S.; Wang, J.; Chen, H.-L.*; Peng, C.-H.* "Highly Stretchable Free-Standing Poly(acrylic acid)-block-poly(vinyl alcohol) Films Obtained from Cobalt-Mediated Radical Polymerization" Macromolecules 2017, 50, 6054.

  12. Wang, F.-S.; Yang, T.-Y.; Hsu, C.-C.; Chen, Y.-J.; Li, M.-H.; Hsu, Y.-J.; Chuang, M.-C.; Peng, C.-H.* "The Mechanism and Thermodynamic Studies of CMRP: Different Control Mechanisms Demonstrated by CoII(TMP), CoII(salen*), and CoII(acac)2 Mediated Polymerization and The Correlation of Reduction Potential, Equilibrium Constant, and Control Mechanism" Macromol. Chem. Phys. 2016, 217, 422. (Invited paper and Cover page for special issue of Young Talents in Polymer Science)

  13. Chen, Y.-J.; Wu, B.-J.; Wang, F.-S.; Chi, M.-H.; Chen, J.-T.*; Peng, C.-H.* "Hybridization of CMRP and ATRP: A Direct Living Chain Extension from Poly(vinyl acetate) to Poly(methyl methacrylate) and Polystyrene" Macromolecules 2015, 48(19), 6832.

  14. Zhao, Y.; Yu, M.; Zhang, S.; Wu, Z.; Liu, Y.; Peng, C.-H.*; Fu, X.* "A Well-defined Versatile Photoinitiator (salen)Co-CO2CH3 for Visible Light Initiated Living/Controlled Radical Polymerization" Chem. Sci. 2015, 6, 2979.

  15. Hsieh, Y.-L.; Huang, N.; Lee, G.-H.; Peng, C.-H.* "Bipyridine-Phenolate Based Aluminum Complexes Mediated Ring-Opening Polymerization of ε-Caprolactone and Lactides with A High Stereoselectivity" Polymer 2015, 72, 281.

  16. Hsieh, Y.-L.; Lin, Y.-C.; Lee, G.-H.; Peng, C.-H.* "Zinc Complexes Coordinated by Bipyridine-Phenolate Ligands as An Efficient Initiator for Ring-Opening Polymerization of Cyclic Esters" Polymer 2015, 56, 237.

  17. Lin, Y.-C.; Hsieh, Y.-L.; Lin, Y.-D.; Peng, C.-H.* "Cobalt Bipyridine Bisphenolate Complex in Controlled/Living Radical Polymerization of Vinyl Monomers" Macromolecules 2014, 47(21), 7362.

  18. Peng, C.-H.*; Yang, T.-Y.; Zhao, Y.; Fu, X.* "Reversible deactivation radical polymerization mediated by cobalt complexes: recent progress and perspectives" Org. Biomol. Chem. 2014, 12, 8580.

  19. Hsu, C.-S.; Yang, T.-Y.; Peng, C.-H.* "Vinyl acetate living radical polymerization mediated by cobalt porphyrins: kinetic–mechanistic studies" Polym. Chem. 2014, 5 (12), 3867.

  20. Liao, C.-M.; Hsu, C.-C.; Wang, F.-S.; Wayland, B. B.; Peng, C.-H.* "Living radical polymerization of vinyl acetate and methyl acrylate mediated by Co(Salen*) complexes" Polym. Chem. 2013, 4, 3098.

書章編輯

  • Chen, Y.-H.; Lu, H.-H.; Li, J.-Q.; Peng, C.-H.* "Catalytic chain transfer polymerization and reversible deactivation radical polymerization of vinyl acetate mediated by cobalt(II) phenoxy-imine complexes" ACS Symp. Ser. 2018, 1284, 335.

專利

獲證專利



  • 嵌段共聚物、分散劑、顏料分散組合物、染料分散組合物以及金屬氧化物分散組合物。中華民國發明專利TW I706974 B

  • 嵌段共聚物及其製備方法。中華民國發明專利 TW I743865

  • Block Copolymer Structure and the Preparing Method Thereof, US11326013B2


申請中專利



  • ブロック共重合体及びその調製方法, JP2022013564A

  • Block Copolymer Structure and the Preparing Method Thereof, EP3932965A1

  • 嵌段共聚物及其制备方法, CN113881001A

更新日期: 2022-10-07