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國立臺灣大學化學系

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蔡蘊明


蔡蘊明
名譽教授, 兼任教授
化學館 B274-3室
電話: 02-3366-1651
傳真: 02-3366-6359
實驗室
研究興趣

  • 研究發展新的自由基反應

  • 在硫化物官能基旁的碳自由基之研究

  • 不對稱自由基環合反應之研究

  • 以矽基酮為自由基受體之自由基反應研究

  • 利用自由基環合反應來合成天然物

  • 有機電激發光聚合物材料之合成研究

簡歷

  • 民國 65 年輔仁大學化學系學士

  • 72 年美國俄亥俄州立大學化學系博士

  • 72-74 年任美國麻省理工學院化學系博士後研究

  • 74-78 年任臺灣大學化學系副教授

  • 78-99 年任臺灣大學化學系教授

  • 96-99 年任臺灣大學化學系副主任

  • 99 年任臺灣大學化學系名譽教授

代表著作

  1. Chen, M.-J.; Tsai, Y.-M. "Radical Cyclizations Of Acylsilanes In The Synthesis Of (+)-Swainsonine And Formal Synthesis Of (–)-Epiquinamide", Tetrahedron, 2011, 67, 1564-1574.

  2. Huang, W.-J.; Huang, C.-C.; Hsin, L.-W.; Tsai, Y.-M.; Lin, C.-T.; Lin, J.-H.; Lee, S.-S. "Improved enamine-type addition of dehydroaporphine using microwave irradiation", Tetrahedron Lett. 2010, 51, 3062-3064.

  3. Chang, C.-C.; Kuo, Y.-H.; Tsai, Y.-M. "The Synthesis Of Carbohydrate Derived Acylsilanes And Their Intramolecular Free Radical Cyclizations With The Formation Of Polyoxygenated Cyclopentanes" , Tetrahedron Lett. 2009, 50, 3805-3808.

  4. Natera, J.; Otero, L.; D'Eramo, F.; Sereno, L.; Fungo, F.; Wang, N.-S.; Tsai, Y.-M.; Wong, K.-T. "Synthesis and Properties of a Novel Cross-Linked Electroactive Polymer Formed from a Bipolar Starburst Monomer" Macromolecules 2009, 42, 626-635.

  5. Chen, M.-J.; Tsai, Y.-M.. "Intramolecular alpha-acylamino radical cyclizations with acylsilanes in the preparation of polyhydroxylated alkaloids: (+)-lentiginosine, (+)-1,8a-di-epi-lentiginosine, and (+)-1,2-di-epi-swainsonine", Tetrahedron Lett. 2007, 48, 6271-6274.

  6. Natera, J.; Otero, L.; Sereno, L.; Fungo, F.; Wang, N.-S.; Tsai, Y.-M.; Hwu, T.-Y.; Wong, K. "A Novel Electrochromic Polymer Synthesized through Electropolymerization of a New Donor-Acceptor Bipolar System", Macromolecules 2007, 40, 4456-4463.

  7. Ueng, S.-H.; Chen, M.-J.; Chu, S.-F.; Shao, Y.-F.; Fan, G.-T.; Chang, S.-Y.; Tsai, Y.-M. "The Scope and Limitations About a 1,3-Stannyl Shift Promoted Intramolecular Cyclizations of a-Stannyl Radicals with a Formyl Group", J. Org. Chem.2006, 71, 1502-1512.

  8. Cheng, M. F.; Yu, H.-M.; Ko, B.-W.; Chang, Y.; Chen, M.-Y.; Chen, W.-S.; Ho, T.-I.; Tsai, Y.-M.; Fang, J.-M. "Practical synthesis of potential endothelin receptor antagonists of 1,4-benzodiazepine-2,5-dione derivatives bearing substituents at the C3-, N1- and N4-postions",Org. Biomol. Chem.2006, 4, 510-518.

  9. Collins, T. R.; Hsieh, T.-s.* "Monitoring the Topoisomerase II DNA Gate Conformational Change with Fluorescence Resonance Energy Transfer" Methods in Mol. Biol. 2009, 582, 59–70.

  10. Tang, K.-H.; Liao, F.-Y.; Tsai, Y.-M. "The study of intramolecular tandem radical cyclizations of acylsilanes with radicalphiles attached on silicon", Tetrahedron, 2005, 61, 2037-2045.

  11. Huang, J.-M.; Hong, S.-C.; Wu, K.-L.; Tsai, Y.-M. "Stereoselective construction of the pyrrolizidine bridgehead stereochemistry by the adjacent hydroxyl group in the synthesis of (+)-heliotridine and (-)-retronecine", Tetrahedron Lett. 2004, 45, 3047-3050.

更新日期: 2019-12-12